Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski PDF

By Krzysztof Matyjaszewski

ISBN-10: 0841219591

ISBN-13: 9780841219595

ISBN-10: 0841238545

ISBN-13: 9780841238541

Provides new advancements in controlled/living radical polymerization in 3 components: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally comprises synthesis and characterization of many new materials.

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Decomposition of the photoinitiator MMMP (a-methyl-4(methylmercapto)-a-morpholino propiophenone). 7 Monomer Conversion, Χ Figure 3. Log calculated for different time ranges after a laser pulse at t = 0 for MA (circles) and DMA (squares) at 1000 bar and 40°C. 5 s (full symbols) for DMA. In Figure 4, a plot similar to the one in Figure 3 is shown for M M A (circles) and D A (squares) homopolymerizations at 40°C. With M M A , the difference between the two associated values is small at low degrees of monomer conversion but becomes significant above 20 % conversion.

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Hutchinson, R. ; Olaj, O. ; Russell, G . ; van Herk, A . M. Macromol. Chem. Phys. 1997, 198, 1545. Listigover, Ν . ; Georges, M . K . ; Odell, P. G . ; Keoshkerian, B . Macromolecules 1996, 29, 8992. ; Fischer, H . Macromolecules 2000, 33, 4403. ; Fischer, H . J. Amer. Chem. Soc. 2001, 123, 2849, and references therein. This was not recognized in our earlier work11b inspite of a thoughtful remark of a referee. D . Bertin, O. Guerret, private communication. ; Fukuda, T. Macromolecules 2003, 36, 908.

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Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski

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