Read e-book online Bifunctional Molecular Catalysis PDF

By Takao Ikariya, Masakatsu Shibasaki

ISBN-10: 3642207308

ISBN-13: 9783642207303

Masakatsu Shibasaki, Motomu Kanai, Shigeki Matsunaga, and Naoya Kumagai: Multimetallic Multifunctional Catalysts for uneven Reactions.- Takao Ikariya: Bifunctional transition metal-based molecular catalysts for uneven syntheses.- Chidambaram Gunanathan and David Milstein: Bond Activation through Metal-Ligand Cooperation: layout of ”Green” Catalytic Reactions in response to Aromatization-Dearomatization of Pincer Complexes.- Madeleine C. Warner, Charles P. Casey, and Jan-E. Bäckvall: Shvo’s Catalyst in Hydrogen move Reactions.- Noritaka Mizuno, Keigo Kamata, and Kazuya Yamaguchi: Liquid-Phase Selective Oxidation by means of Multimetallic energetic websites of Polyoxometalate-Based Molecular Catalysts.- Pingfan Li and Hisashi Yamamoto: Bifunctional Acid Catalysts for natural Synthesis.- Jun-ichi Ito, Hisao Nishiyama: Bifunctional Phebox Complexes for uneven Catalysis.

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Chen Z, Furutachi M, Kato Y, Matsunaga S, Shibasaki M (2009) Angew Chem Int Ed 48:2218 21. Kato Y, Furutachi M, Chen Z, Mitsunuma H, Matsunaga S, Shibasaki M (2009) J Am Chem Soc 131:9168 22. Chen Z, Morimoto H, Matsunaga S, Shibasaki M (2008) J Am Chem Soc 130:2170 23. Chen Z, Yakura K, Matsunaga S, Shibasaki M (2008) Org Lett 10:3239 24. Xu Y, Lu G, Matsunaga S, Shibasaki M (2009) Angew Chem Int Ed 48:3353 25. Shepherd NE, Tanabe H, Xu Y, Matsunaga S, Shibasaki M (2010) J Am Chem Soc 132:3666 26.

32 Asymmetric Transfer Hydrogenation of Simple and Functionalized Aromatic Ketones with the Bifunctional Catalysts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Catalytic Hydrogenation of Carboxylic Acid Derivatives Containing C¼O Double Bonds with Bifunctional Molecular Catalysts . . . . . . . . . . . . . . . . . . . . . . . 1 Heterolytic Cleavage of Molecular Hydrogen with Bifunctional Catalysts . . . . . . 2 Hydrogenation of Imides .

52 1 Introduction A deep understanding of the mechanism of catalytic transformations as well as a great insight into the architecture of molecular catalysts has enabled rational design of sophisticated metal-based molecular catalysts [1–4]. Particularly, much effort has been recently paid to the development of bifunctional molecular catalysts based on the combination of two or more active sites working in concert, to attain highly efficient molecular transformations for organic synthesis.

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Bifunctional Molecular Catalysis by Takao Ikariya, Masakatsu Shibasaki

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