Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip's Complex Macromolecular Architectures: Synthesis, PDF

By Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip Du Prez

ISBN-10: 0470825138

ISBN-13: 9780470825136

ISBN-10: 0470825154

ISBN-13: 9780470825150

The sphere of CMA (complex macromolecular structure) stands on the innovative of fabrics technological know-how, and has been a locus of severe learn task lately. This ebook provides an in depth description of the synthesis, characterization, and self-assembly of recently-developed complicated architectural fabrics with a couple of capability functions.

The architectural polymers, together with bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are brought bankruptcy by means of bankruptcy within the ebook. particularly, the ebook additionally emphasizes the subject of artificial breakthroughs by way of living/controlled polymerization for the reason that 2000.

in addition, well known authors give a contribution on unique issues reminiscent of helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, that have attracted huge curiosity as novel polymer fabrics with power destiny purposes. moreover, contemporary advances in reactive mixing completed with well-defined end-functionalized polymers are mentioned from an commercial perspective. issues on polymer-based nanotechnologies, together with self-assembled architectures and suprastructures, nano-structured fabrics and units, nanofabrication, floor nanostructures, and their AFM imaging research of hetero-phased polymers also are incorporated.

  • Provides complete assurance of lately constructed complex architectural materialsContent:
    Chapter 1 Cyclic and Multicyclic Topological Polymers (pages 1–19): Takuya Yamamoto and Yasuyuki Tezuka
    Chapter 2 Ultrarapid techniques to gentle Macromolecular Conjugation (pages 21–52): Andrew J. Inglis and Christopher Barner?Kowollik
    Chapter three Synthesis and Self?Assembly of Hydrogen?Bonded Supramolecular Polymers (pages 53–95): Wolfgang H. Binder, Claudia Enders, Florian Herbst and Katharina Hackethal
    Chapter four contemporary man made advancements in Miktoarm famous person Polymers with greater than 3 diverse palms (pages 97–132): Akira Hirao, Mayumi Hayashi, Tomoya Higashihara and Nikos Hadjichristidis
    Chapter five targeted Synthesis of Dendrimer?Like Star?Branched Polymers, a brand new category of Well?Defined Hyperbranched Polymers (pages 133–167): Hee?Soo Yoo and Akira Hirao
    Chapter 6 Arborescent Polymers with a Mesoscopic Scale (pages 169–194): Toufic Nabil Aridi and Mario Gauthier
    Chapter 7 Hyperbranched Glyco?Conjugated Polymers (pages 195–227): Toshifumi Satoh and Toyoji Kakuchi
    Chapter eight hugely Branched sensible Polymer Architectures by means of Click?Chemistry ideas (pages 229–265): Mieke Lammens and Filip Du Prez
    Chapter nine residing Alkene Polymerization for Polyolefin Architectures (pages 267–316): Amelia M. Anderson?Wile, Joseph B. Edson and Geoffrey W. Coates
    Chapter 10 Precision Polyolefins (pages 317–347): Erik B. Berda and Kenneth B. Wagener
    Chapter eleven Polyhomologation: The residing Polymerization of Ylides (pages 349–376): Jun Luo and Kenneth J. Shea
    Chapter 12 Phenylenevinylene Homopolymers and Block Copolymers through Ring?Opening Metathesis Polymerization (pages 377–393): Chin?Yang Yu and Michael L. Turner
    Chapter thirteen Block Copolymers Containing Rod Segments (pages 395–429): Tomoya Higashihara and Mitsuru Ueda
    Chapter 14 Synthesis of Well?Defined Poly(meth)acrylamides with assorted Stereoregularity through residing Anionic Polymerization (pages 431–460): Takashi Ishizone
    Chapter 15 complicated Macromolecular Chimeras (pages 461–489): Hermis Iatrou, Marinos Pitsikalis, Georgios Sakellariou and Nikos Hadjichristidis
    Chapter sixteen Self?Assembly and purposes of Polyferrocenylsilane Block Copolymers (pages 491–526): George R. Whittell, Jessica Gwyther, David A. Rider and Ian Manners
    Chapter 17 sensible Polymeric Nanostructures ready by means of Self?Assembly and past (pages 527–567): Rachel okay. O'Reilly
    Chapter 18 Morphologies of Block and Star?Branched Polymers with 3 elements (pages 569–591): Hirokazu Hasegawa
    Chapter 19 Morphologies and Photophysical homes of Conjugated Rod–Coil Block Copolymers (pages 593–622): Chi?Ching Kuo, Cheng?Liang Liu and Wen?Chang Chen
    Chapter 20 Bulk Self?Assembly of Linear Hybrid Polypeptide?Based Diblock and Triblock Copolymers (pages 623–645): Sebastien Lecommandoux
    Chapter 21 AFM research of Comb (Co)Polymers with advanced Chain structure (pages 647–683): Michel Schappacher and Alain Deffieux
    Chapter 22 Tunable Thermoresponsive Polymers by way of Molecular layout (pages 685–715): Richard Hoogenboom
    Chapter 23 Fluorine?Containing Block Copolymers: Synthesis and alertness as a Template for Nanocellular and Porous constructions utilizing Supercritical Carbon Dioxide (pages 717–737): Hideaki Yokoyama and Kenji Sugiyama
    Chapter 24 Architectural Polymers, Nanostructures, and Hierarchical constructions from Block Copolymers (pages 739–761): Ian Wyman and Guojun Liu
    Chapter 25 Block Copolymer Nanostructured skinny movies for complicated Patterning (pages 763–790): Michelle A. Chavis, Evan L. Schwartz and Christopher okay. Ober
    Chapter 26 Ring Polymers: powerful Isolation and specified homes (pages 791–821): Haskell W. Beckham

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Additional resources for Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly

Example text

1998) A New strategy for the synthesis of macrocycles. The polyhomologation of boracyclanes. The Journal of Organic Chemistry, 63, 5746–5747. , Ohta, K. et al. (2010) Effective click construction of bridged- and spiro-multicyclic polymer topologies with tailored cyclic prepolymers (kyklo-telechelics). Journal of the American Chemical Society, 132, 14790–14802. , Aoki, K. et al. (2007) HPLC characterization of cyclization reaction product obtained by end-to-end ring closure reaction of a telechelic polystyrene.

2008a) Synthesis of macrocyclic copolymer brushes and their self-assembly into supramolecular tubes. Science, 319, 1512–1515. Schappacher, M. and Deffieux, A. (2008b) Atomic force microscopy imaging and dilute solution properties of cyclic and linear polystyrene combs. Journal of the American Chemical Society, 130, 14684–14689. C. (2003) DNA in a material world. Nature, 421, 427–431. B. (1998) A New strategy for the synthesis of macrocycles. The polyhomologation of boracyclanes. The Journal of Organic Chemistry, 63, 5746–5747.

2. , 1999). 2 Overview of ultrarapid and mild conjugation chemistries. J. Inglis and C. Barner-Kowollik, “Ultra rapid approaches to mild macromolecular conjugation,” Macromolecular Rapid Communications, 2010, 31, 14, 1247–1266. Ó Wiley-VCH Verlag GmbH & Co. ) construction of precisely defined polymeric materials. , 2009). Although making use of readily available materials and no catalyst, elevated temperatures (>110  C) and extended reaction times (36–120 h) are severe limitations. , 2006). 3 Chemical structures of the RAFTagents that may be utilized in RAFT-HDA click chemistry.

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Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly by Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip Du Prez


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