By Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip Du Prez
The sphere of CMA (complex macromolecular structure) stands on the innovative of fabrics technological know-how, and has been a locus of severe learn task lately. This ebook provides an in depth description of the synthesis, characterization, and self-assembly of recently-developed complicated architectural fabrics with a couple of capability functions.
The architectural polymers, together with bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are brought bankruptcy by means of bankruptcy within the ebook. particularly, the ebook additionally emphasizes the subject of artificial breakthroughs by way of living/controlled polymerization for the reason that 2000.
in addition, well known authors give a contribution on unique issues reminiscent of helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, that have attracted huge curiosity as novel polymer fabrics with power destiny purposes. moreover, contemporary advances in reactive mixing completed with well-defined end-functionalized polymers are mentioned from an commercial perspective. issues on polymer-based nanotechnologies, together with self-assembled architectures and suprastructures, nano-structured fabrics and units, nanofabrication, floor nanostructures, and their AFM imaging research of hetero-phased polymers also are incorporated.
Provides complete assurance of lately constructed complex architectural materialsContent:
Chapter 1 Cyclic and Multicyclic Topological Polymers (pages 1–19): Takuya Yamamoto and Yasuyuki Tezuka
Chapter 2 Ultrarapid techniques to gentle Macromolecular Conjugation (pages 21–52): Andrew J. Inglis and Christopher Barner?Kowollik
Chapter three Synthesis and Self?Assembly of Hydrogen?Bonded Supramolecular Polymers (pages 53–95): Wolfgang H. Binder, Claudia Enders, Florian Herbst and Katharina Hackethal
Chapter four contemporary man made advancements in Miktoarm famous person Polymers with greater than 3 diverse palms (pages 97–132): Akira Hirao, Mayumi Hayashi, Tomoya Higashihara and Nikos Hadjichristidis
Chapter five targeted Synthesis of Dendrimer?Like Star?Branched Polymers, a brand new category of Well?Defined Hyperbranched Polymers (pages 133–167): Hee?Soo Yoo and Akira Hirao
Chapter 6 Arborescent Polymers with a Mesoscopic Scale (pages 169–194): Toufic Nabil Aridi and Mario Gauthier
Chapter 7 Hyperbranched Glyco?Conjugated Polymers (pages 195–227): Toshifumi Satoh and Toyoji Kakuchi
Chapter eight hugely Branched sensible Polymer Architectures by means of Click?Chemistry ideas (pages 229–265): Mieke Lammens and Filip Du Prez
Chapter nine residing Alkene Polymerization for Polyolefin Architectures (pages 267–316): Amelia M. Anderson?Wile, Joseph B. Edson and Geoffrey W. Coates
Chapter 10 Precision Polyolefins (pages 317–347): Erik B. Berda and Kenneth B. Wagener
Chapter eleven Polyhomologation: The residing Polymerization of Ylides (pages 349–376): Jun Luo and Kenneth J. Shea
Chapter 12 Phenylenevinylene Homopolymers and Block Copolymers through Ring?Opening Metathesis Polymerization (pages 377–393): Chin?Yang Yu and Michael L. Turner
Chapter thirteen Block Copolymers Containing Rod Segments (pages 395–429): Tomoya Higashihara and Mitsuru Ueda
Chapter 14 Synthesis of Well?Defined Poly(meth)acrylamides with assorted Stereoregularity through residing Anionic Polymerization (pages 431–460): Takashi Ishizone
Chapter 15 complicated Macromolecular Chimeras (pages 461–489): Hermis Iatrou, Marinos Pitsikalis, Georgios Sakellariou and Nikos Hadjichristidis
Chapter sixteen Self?Assembly and purposes of Polyferrocenylsilane Block Copolymers (pages 491–526): George R. Whittell, Jessica Gwyther, David A. Rider and Ian Manners
Chapter 17 sensible Polymeric Nanostructures ready by means of Self?Assembly and past (pages 527–567): Rachel okay. O'Reilly
Chapter 18 Morphologies of Block and Star?Branched Polymers with 3 elements (pages 569–591): Hirokazu Hasegawa
Chapter 19 Morphologies and Photophysical homes of Conjugated Rod–Coil Block Copolymers (pages 593–622): Chi?Ching Kuo, Cheng?Liang Liu and Wen?Chang Chen
Chapter 20 Bulk Self?Assembly of Linear Hybrid Polypeptide?Based Diblock and Triblock Copolymers (pages 623–645): Sebastien Lecommandoux
Chapter 21 AFM research of Comb (Co)Polymers with advanced Chain structure (pages 647–683): Michel Schappacher and Alain Deffieux
Chapter 22 Tunable Thermoresponsive Polymers by way of Molecular layout (pages 685–715): Richard Hoogenboom
Chapter 23 Fluorine?Containing Block Copolymers: Synthesis and alertness as a Template for Nanocellular and Porous constructions utilizing Supercritical Carbon Dioxide (pages 717–737): Hideaki Yokoyama and Kenji Sugiyama
Chapter 24 Architectural Polymers, Nanostructures, and Hierarchical constructions from Block Copolymers (pages 739–761): Ian Wyman and Guojun Liu
Chapter 25 Block Copolymer Nanostructured skinny movies for complicated Patterning (pages 763–790): Michelle A. Chavis, Evan L. Schwartz and Christopher okay. Ober
Chapter 26 Ring Polymers: powerful Isolation and specified homes (pages 791–821): Haskell W. Beckham
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Additional resources for Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly
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2. , 1999). 2 Overview of ultrarapid and mild conjugation chemistries. J. Inglis and C. Barner-Kowollik, “Ultra rapid approaches to mild macromolecular conjugation,” Macromolecular Rapid Communications, 2010, 31, 14, 1247–1266. Ó Wiley-VCH Verlag GmbH & Co. ) construction of precisely defined polymeric materials. , 2009). Although making use of readily available materials and no catalyst, elevated temperatures (>110 C) and extended reaction times (36–120 h) are severe limitations. , 2006). 3 Chemical structures of the RAFTagents that may be utilized in RAFT-HDA click chemistry.
Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly by Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip Du Prez