Download e-book for iPad: The Chemical Bond : Chemical Bonding Across the Periodic by Gernot Frenking, Sason Shaik

By Gernot Frenking, Sason Shaik

ISBN-10: 0470746599

ISBN-13: 9780470746592

ISBN-10: 3527307486

ISBN-13: 9783527307487

ISBN-10: 3527333142

ISBN-13: 9783527333141

ISBN-10: 3527333150

ISBN-13: 9783527333158

ISBN-10: 3527334157

ISBN-13: 9783527334155

ISBN-10: 3527664653

ISBN-13: 9783527664658

ISBN-10: 3527664661

ISBN-13: 9783527664665

ISBN-10: 352766467X

ISBN-13: 9783527664672

ISBN-10: 3527664688

ISBN-13: 9783527664689

ISBN-10: 3527664696

ISBN-13: 9783527664696

ISBN-10: 352766470X

ISBN-13: 9783527664702

ISBN-10: 3527664718

ISBN-13: 9783527664719

ISBN-10: 3527664726

ISBN-13: 9783527664726

This can be the suitable supplement to ''Chemical Bonding - around the Periodic Table'' through an identical editors, who're of the head scientists engaged on this subject, every one with wide adventure and demanding connections in the community.
The ensuing ebook is a distinct review of different methods used for describing a chemical bond, together with molecular-orbital dependent, valence-bond established, ELF, target and density-functional established tools. It takes into consideration the various advancements that experience taken position within the box over the last few a long time as a result of quick advances in quantum chemical types and swifter computers.

Show description

Read or Download The Chemical Bond : Chemical Bonding Across the Periodic Table PDF

Similar physical chemistry books

David A. Mazziotti's Advances in Chemical Physics, Reduced-Density-Matrix PDF

An updated account of this state-of-the-art study in a constant and comprehensible framework, of precise curiosity to specialists in different components of digital constitution and/or quantum many-body concept. it is going to serve both good as a self-contained consultant to studying approximately diminished density matrices both via self-study or in a school room in addition to a useful source for realizing the severe developments within the box.

New PDF release: The Plasma Chemistry of Polymer Surfaces: Advanced

This booklet illustrates plasma homes, polymer features, floor specifics, and the way to purposefully mix plasma and polymer chemistry. In so doing, it covers plasma polymerization, floor functionalization, etching, crosslinking, and deposition of monotype functional-group-bearing plasma polymers.

Carbonic Anhydrases as Biocatalysts: From Theory to Medical by Claudiu T Supuran, Giuseppina De Simone PDF

Carbonic anhydrases (CAs, EC four. 2. 1. 1) are ubiquitous metalloenzymes, current all through such a lot dwelling organisms and encoded by means of 5 evolutionarily unrelated gene households. The Carbonic Anhydrases as Biocatalysts:From thought to scientific and business functions provides info at the becoming curiosity within the learn of this enzyme family members and their functions to either drugs and biotechnology.

Extra info for The Chemical Bond : Chemical Bonding Across the Periodic Table

Sample text

290, 488–494. 1 Introduction Chemical experience has shown that compounds with multiple bonds between heavier main-group atoms are much more difficult to synthesize, and that they often exhibit greatly different geometries than their counterparts of the first octal row [1]. The most prominent examples are the group-14 homologues of ethylene and acetylene. The chemical bonds in H2 C=CH2 and HC≡CH are archetypical examples for σ- and π-bonding in planar alkenes and linear alkynes. 1) [3]. Experimental evidence is in agreement with the theoretical predictions.

2005) Chem. Eur. , and Strohmann, C. (2011) Eur. J. Inorg. , 1454–1465, and references therein. E. (1977) J. Chem. , 66, 5769–5776. J. C. (1986) J. Am. Chem. A. J. III, (1987) J. Am. Chem. , and Liddell, M. (1994) J. Am. Chem. , 116, 9620–9633. P. (1999) Chem. , 99, 3463–3503. A. A. III, (1986) J. Phys. , 90, 998–1001; (b) Trinquier, G. -P. (1987) J. Am. Chem. , 109, 5303–5315. , and Frenking, G. (2005) J. Am. Chem. , 127, 6290–6299. T. (1983) Polar Covalence, Academic Press, New York. References 48.

At the inversion transition state, the N–H bonds in NH3 still exhibit the nominal sp2 hybridization for a trigonal coordination. The substantial and worsening hybridization defects are particularly notable for the N–H bonds in NH2 F and NHF2 ; and then they are also significant for the N–F bonds in NHF2 and especially in NF3 . One might therefore expect to have very large barriers for species like PF3 , AsF3 , SbF3 , or BiF3 . However, in these cases it has been found unexpectedly by computations that inversion proceeds not via a D3h -symmetrical trigonal but via a C2v -symmetrical Y-shaped transition state, leading to lower barriers and, indeed, an inverted trend with the barriers decreasing down the group [43].

Download PDF sample

The Chemical Bond : Chemical Bonding Across the Periodic Table by Gernot Frenking, Sason Shaik


by Anthony
4.2

Rated 4.80 of 5 – based on 40 votes